I would soak it in easing fluid then support the back of the bush with either copper or wood, not steel, to avoid damaging it then gently tap the domed end. If the valve is so stuck that the bush came out when you tried to get it out it is pretty well stuck.

Be careful because the shaft of the valve can bend ever so slightly and then it will be no further use. You also do not want to put a bur on the edges of the bush.
The notches are to bleed oil out, the two large ones go to the rear as you replace the bush.
If your valve is that stuck it probably has a steel ring not an "O" ring and this has rusted to the bush. They are very fragile and easily broken when you replace the valve even with the special tool. I gently push the valve into the bush until it rests on the ring, then ease the ring into the bore with a small screwdriver at the same time gently pushing on the valve. I also apply a heavy coat of MS grease to the ring which helps hold it in place.
The bush may need a drop of Loctite to help hold it in place if it is a loose fit but do not get any on the inside.
The unload valve works at about 11 psi and this is maintained by the valve on the bottom of the return filter so check that the valve is there and the filter is OK.